Python 3.4.4 - pip collection error -

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i appreciate on below query - i've been trying pip work best of day , struggling.

regardless of module try install keep getting "could not find version satisfies requirement openpyxl (from version s: ) no matching distribution found openpyxl

please see screenshot below of error:

enter image description here

i've looked @ around website, including following posts, installing pip still unsure why isn't working.

'pip' not recognized internal or external command

fatal error in launcher: unable create process using ""c:\program files (x86)\python33\python.exe" "c:\program files (x86)\python33\pip.exe""

any massively appreciated!

have tried check internet connection? screenshot, seems cannot access url follow:.
https://pypi.python.org/simple/openpyxl/


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